]]>
Skip to main content

#32 Foam formation within ceramic glazes: how to deal with the problem?

ZS Lab
You know that

Among the several issues that may occur along the glazing line, the excessive foaming of the glaze is one of the most frequent and problematic. The phenomenon is already visible on the surface of the glaze inside the stirring systems but the consequences of its presence can…

#31 Ceramic glaze application & technical defects: the TV effect

ZS Lab
You know that

Speaking of ceramic glaze applications and technical defects, one of the strangest and most interesting is the "TV effect". It consists of a preferential migration of the glaze towards the perimeters of the tile that produces in those areas a thickening of the glaze. The…

#30 Excessive viscosity of the slip: causes & remedies

ZS Lab
You know that

Viscosity (or viscous friction coefficient) measures a substance's attitude on generating friction between its layers. In other words, it defines the fluid resistance to its proper flow. The viscosity value of the barbottina can sometimes rapidly and suddenly change and in case…

#29 Glazes and engobes bacterial degradations: technical & aesthetic consequences

ZS Lab
You know that

All process water involved in ceramic production, both tap and well waters, usually contains a variable percentage of bacteria. And the same applies to inorganic raw materials used in the grinding process to produce the semi-finished products that will be later applied along the…

#28 Digital inks for ceramic production: what do we need to know?

ZS Lab
You know that

In the last few years the ceramic industry has been rapidly evolving thanks to the progressive digitalization of the some of the processes. In this regard, the digital ink decoration system plays one of the most important role. What is a digital ink for ceramic? What is its…

#27 Ceramic glazes, surface tension & chemicals

ZS Lab
You know that

Surface tension is the tendency of liquid surfaces at rest to shrink into the minimum surface area possible. In general, to get a proper glaze application, it is always important to work on the fluid's surface tension by decreasing or, more generally, adjusting it, until you…

#26 Ceramic slips & rheological behavior

ZS Lab
You know that

In general, wet grinding systems as well as atomization systems, offer the best performance and the best production results only when chemical and physical features of slips are constant for the duration of entire process. More precisely, the optimal process is developed when the…

#25 Formaldehyde, ceramic production and environmental impact

ZS Lab
You know that

The Italian ceramic industry has been involved for years in a very important goal: the reduction of environmental impact. For this reason it is constantly tested in order to prove its right performances as well as to ensure compliance with the strictest standards. Formaldehyde…

#24 Ceramic suspensions & rheological behavior

ZS Lab
You know that

Rheology is the science that deals with the flow and the strain rate of matter. It’s a branch of physics that studies the origin, nature and deformation’s characteristics of a matter under the influence of external forces, with particular regard to non-Newtonian liquids. Its…

#23 Deflocculation of ceramic mixtures: what are they and how do they work?

ZS Lab
You know that

The flocculation of ceramic mixtures is a problem marked by a progressive aggregation of the solid particles and it often takes place due to phenomena of electrostatic attraction between the clay micelles in suspension. This process leads to a significant increase in viscosity…

#22 Ceramic glazes, dusting phenomena & digital printing decoration

ZS Lab
You know that

What do we mean with “dusting phenomena”? What are the features of a glaze marked by this characteristic? In general, we are talking about a glaze that shows a low cohesion after application by means of traditional airless spray systems. This lack of cohesion is not only…

#21 Surface protection treatments, emissions & regulations

ZS Lab
You know that

Surface treatments’ target is to protect the surface, improving its performance without changing the basic features of the tile. More generally, tiles (treated or not treated) must comply with regulations and market’s target that can obviously change according to the client and…

#20 Ceramic production, chemicals & environmental impact

ZS Lab
You know that

This dissertation aims to refocus, from a special and provocative perspective, the role of chemicals used in ceramics: from the beginning to the end of the entire process, that is from the grinding of the clays that form the basis of the ceramic mixture up to the firing cycle. …

#19 Ceramic glazes: application systems, rheology & synthetic chemicals

ZS Lab
You know that

Ceramic glazes can be applied along the glazing line by means of different systems. The most popular and widespread is the airless spray system, even if vela and bell systems are still in use. Whatever is the choise made by ceramic producers, the glaze's rheology must be always…

#18 Water-based digital glues: what benefit do they promote?

ZS Lab
You know that

Chemically speaking, water-based digital glues can be generally considered as organic polymers and inorganic components (when present) in water and polar solvents. Their chemical nature, unlike that of solvent-based digital glues, is firstly characterized by the elimination of…

#17 Digital glues: what are they and how do they work?

ZS Lab
You know that

There have been for years on the market different kind of DIGITAL GLUES for ceramic production, applied process by means of piezoelectric inkjet systems. Although each of them interacts with powders and/or grit in different ways, there are currently two main categories that must…

#16 Black core: origins of the defect and problem-solving actions

ZS Lab
You know that

The black core is a more or less localized area characterized by a brown/black (or even white) color, clearly visible in the thickness of the final ceramic tile. Its presence is usually sign of inadequate oxidation and it has not to be considered a defect that compromise the…

#15 Glazes' repellency phenomena: additives for applications before and after digital printing process

ZS Lab
You know that

The ink-jet decoration has surely eliminated several critical issues bringing out, however, new and more complex problems. Among them, the most popular concerns the water repellency phenomena that arise due to the lack of chemical compatibility between inks based on non-polar…

#14 Chemicals for ceramic mixtures: an overview

ZS Lab
You know that

The ceramic mixture usually used in ceramic production, largely consists of inorganic raw materials (clay, feldspar, sand, etc.), grinding water and chemical. These mixtures, since they must be properly managed in the various stages of the production process - from grinding to…

#13 Superficial halos formation during the drying process

ZS Lab
You know that

As is well known, the ceramic mixture after being atomized is subjected, during the forming phase, to very high pressures (over 400 Kg/cm2) that are necessary for the creation of the ceramic body. The raw tile, even after pressing, contains a water amount (residual humidity)…

#12B Ceramic glaze applications & additives in use

ZS Lab
You know that

The ceramic glaze application is one of the most delicate steps of the ceramic production process. To get high levels of performance, the glaze must have accurate rheological characteristics that take into account the specific and different application conditions of the…

#12A Ceramic glaze applications & additives in use

ZS Lab
You know that

The ceramic glaze application is one of the most delicate steps of the ceramic production process. To get high levels of performance, the glaze must have accurate rheological characteristics that take into account the specific and different application conditions of the…

#11 Dry grit analogical applications (GRANICER 6000)

ZS Lab
You know that

The dry grit application system is a mode of the ceramic production process that companies are looking at with increasing attention and that somehow has already found its circulation thanks to the wide use of digital systems that focus not only on the application of inks but also…

#10 Digital glazing by means of non-piezoelectric systems

ZS Lab
You know that

Ceramic glaze application – both before and after the digital printing process – mostly occurs by means of analogical systems (spray wet application). For some time, however, new kind of machines that do not leverage digital technology (inkjet – piezoelectric) has joined the…

#09 Mechanical resistance of raw and dried tiles

ZS Lab
You know that

The mechanical resistance value of raw ceramics tiles is normally regulated by the UNI EN ISO 10545/4 and it is measured by a device that is called chrometer. This is a specific precision tool that is able to define the breaking load and the flexural strength of the ceramic…

#08 Pin-holes on ceramic surface after firing: causes and remedies

ZS Lab
You know that

Following the ceramic body forming stages and subsequent digital printing steps, the ceramic production process involves a final application of grits or glazes, sometimes in significant amounts. Failure to apply the correct process parameters can sometimes lead to issues in…

#07 Ceramic surfaces & antibacterial properties

ZS Lab
You know that

Antibacterial protections, already used in several fields of industrial production, had become in more recent times a central issue of ceramic tile’s production. Market interest, also pushed by the recent events, has speeded up the research within the labs in order to boost a…

#06 Clogging of spray nozzles during grit application

ZS Lab
You know that

Grit suspensions applied by means of spray systems applications are usually prepared in the glazes’ grinding department. The three main ingredients of the suspension are poured inside tanks provided with stirrers.

#05 Cracks and silica recession inside the pores after surface protection treatments: what's going on?

ZS Lab
You know that

As we all know, lapping and polishing processes that are necessary to provide ceramic tiles with the required aesthetic features, both involve the removal of a very thin layer of glaze that is on the very external part of the tile.

#04 Process water and production problems: what do you need to know?

ZS Lab
You know that

Process water play a very important role within ceramic activities, being involved in a wide range of production’s steps. If one the one hand they are strictly necessary to the course of the work, they can lead on the other hand to problems when they do not fits the required…

#03 Bacterial degradation of semi-finished materials. What to do?

ZS Lab
You know that

In ceramic, semi-finished products are all those materials (in our case, aqueous suspensions) that are produced beside the main production line and that are used in several phases of the process, mostly along the glazing line.

#02 Why do slurry jellify during stocking?

ZS Lab
You know that

As many know, slurries (the mix or SUSPENSION of water, clays and raw materials that form the basic ceramic mixture) before being processed within the atomizers, can rest for shorter or longer time inside storage tanks, where they undergo to a slow and constant stirring action in…

#01 Why do tiles explodes within the kiln?

ZS Lab
You know that

During firing cycle, tiles usually start to gradually and constantly heat up. During the heating process, it obviously starts the water evaporation process. Water that is present both on the surface and (overall) inside the ceramic body.

Digital Printing: Options & Challenges in heavy clay ceramics (2)

ZS Lab
You know that

In the 6/2019 edition of Zi Brick and Tile Industry International, the first part of this article informed readers about the technical aspects of digital printing systems. This part of the article examines the necessary preparatory work and explains the file creation process. All…

Silver, Titania and antibacterial ceramics: the chemistry point of view

ZS Lab
You know that

Silver is a noble metal with a long-standing tradition. It is a trace element even present in organism’s tissues. Even though in small quantities, it is also taken by humans through food. Silver is being used in many medical and industrial applications as well as in different…

Ceramic production and antibacterial surfaces: what they are, how they work and possible developments

ZS Lab
You know that

Due to the recent events that have brought to public attention the increasingly tightening requirements in terms of cleaning and health protection, the ceramic district - that for some time has been offering to the market surfaces with “anti-bacterial properties” - is working…

Primers for inkjet: mechanisms and functionings

ZS Lab
You know that

Ceramic industry is today inseparably linked to the use of digital printer machines that involve the use of pigmented liquid inks. These new production systems have therefore required the development of specific mediums able to improve the printing process in terms of definition…

Surface protection treatments: technical porcelain stoneware and new scenarios

ZS Lab
You know that

Changes in taste perception together with the evolution of high performing and sophisticated production technologies, have led to the assertion on the markets of ceramic surface that aesthetically reproduce a wide range of natural materials.

Chemicals for ceramic production: a focus on deflocculants and binders

ZS Lab
You know that

As we know, most of the ceramic production processes depend on suspensions or more generally chemical dispersions of ceramic powder in a liquid, mostly water. In order to provide the suspension with the right features in terms of stability and workability, (according to the…

Chemical additives involved in ceramic production processes: an overview

ZS Lab
You know that

Chemical additives allow and promote the proper performance of almost all the ceramic production processes. Their importance has been exponentially raising with the coming of the rapid firing cycles that have increased the companies’ productivity, leading to a cost containment. …

How to set up a glazes and engobes' milling department that is highly resistant to bacteria

ZS Lab
You know that

All waters used in ceramic processes, both tap and well water, contain bacteria and microorganisms. The same goes for the inorganic raw materials involved in the milling process: frits, clays, feldspar, nefeline, etc… On this basis, bacterial proliferations can potentially…

Why the use of Sodium Silicate is important for an outstanding ceramic body's deflocculation?

ZS Lab
You know that

Sodium Silicate is an inorganic material that effectively acts within the ceramic body as a fluidifying agent, affecting at the same time other no less relevant aspects. It make it possible to decrease in the formula the amount of organic elements that, due to their…

Ceramic Grits: Development, application evolutions and chemical responses

ZS Lab
You know that

The ceramic industry has recently shown an interest in some of the latest generation glass grits, to be used as final cover on all those product - tiles or slabs - that are subsequently destined for lapping or sanding process.

Ceramic mixture’s flocculation: chemical & phisical reasons and intervenctions

ZS Lab
You know that

The preparation of the ceramic mixture for wet grinding offers two important benefits thanks to the raw materials involved: Optimal dissolution Good homogenisation As we know, the forementioned wet preparation which contains a high amount of solid, is called slurry…

Is it possible to lower the electrical conductivity value of the water used in the ceramic production process?

ZS Lab
You know that

As already highlighted in the news dedicated to grinding water ( What characteristic the grinding water should have to yield a dense slurry? ), controlling the electrical conductivity is essential in order to avoid rheological problems inside the slurry. The grinding water…

Emissions: ceramic firing process & solvent’s chemical composition (used in inkjet inks)

ZS Lab
You know that

The issue of smell and polluting emissions deriving from the firing ceramic process is still a critical topic. In order to understand and solve the problem, it must look at the root of what’s causing it: the chemical composition of digital inks.

How to carefully calculate the dosage of additives for glaze or slurry (in the tub during the production process)?

ZS Lab
You know that

The use of additives in the ceramic production process – specially added to glaze or slurry – is now essential in order to obtain a product with high technical performance and refined aesthetic features marked by attention to detail.

How to calculate the picoliter drainage of a digital print head? (download the calculation form)

ZS Lab
You know that

To calculate the picoliter volume of an ink drop discharged by a single nozzle of an inkjet head print it is necessary to make a couple of simple calculation that keep in mind the following variables

How to manage a full-field grit application?

ZS Lab
You know that

The wet system requires the use of specific medium. On the other side, the dry application takes place using special machines (shot blasting applicators) that can work with two different technologies (roller or belt), both with the same purpose: spreading uniformly the grit on…

Why do the products used for the end-of-line protection treatment should be color matched to the tile?

ZS Lab
You know that

The end-of-line protective treatment – which is recommended after the lapping/polishing process – preserve the ceramic surface from stains and dirt, and it improves the surface’s performance avoiding possible chemical aggressions.

End-of-line superficial treatment: how to avoid dirty surfaces

ZS Lab
You know that

The polishing or lapping process can make the surface delicate and more sensitive: to chemical agents = detergents or aggressive cleaning products to food = lemon juice, coffee, tomatoes

Wet application of grit: how to improve leveling

ZS Lab
You know that

The use of ceramic spray booth is the most widely used method for the wet full field application of grit.

Does the grit applied with digital glues need a final surface fixing?

ZS Lab
You know that

Digital glues, whether water or solvent based, have the ability to fix the glass grit to the ceramic support. However, in case of full field application (when the amount of grit can reach 600/800 grams per square meter), the glue is not able to bind the entire layer of grit.

Why the use of water-based digital adhesives facilitates the application of low, moderate and high quantities of grit

ZS Lab
You know that

The use of water-based digital adhesives facilitates the application (even simultaneous) of low, moderate and high quantities of grit.

Why do water based adhesives offer higher print resolution?

ZS Lab
You know that

Solvent based digital adhesives, like all bulk digital inks, tend to expand in contact with the substrate, thus losing the definition of the grit. Water based digital adhesives have 2 components: alpha and beta. These 2 components, once applied, react very rapidly to create a…

Why polished tiles are less resistant to chemical and stain aggression?

ZS Lab
You know that

The vitreous covering which protects the tiles offers very high performance in terms of resistance to stains and chemical agents. Grinding removes a certain amount of glaze from the surface with the grinding machine disks, creating a very flat surface with a matt or reflective…

Polluting and malodorous emissions due to firing: causes and remedies

ZS Lab
You know that

Despite the considerable benefits of digital inks in ceramic manufacturing, there are some important counterindications. In particular, the increase in polluting emissions and bad odours during combustion of solvent based inks, which is a problem for people living nearby the…

Definition of ink jet decoration: how to improve it

ZS Lab
You know that

Digital inks have had considerable benefits for ceramic decoration, especially in relation to the definition of the graphics. However, the conditions for application of the inks do not always allow an adequate definition to be obtained, especially when intense colourations are…

How to reduce the residual humidity of tiles

ZS Lab
You know that

Ceramic companies are increasingly feeling the need to reduce the water consumption of their glazing lines. This is mainly due to the fact that the residual humidity of tiles entering the kiln must be controlled to stop them exploding during pre-firing: the water generates a…

How to eliminate the hydro-repellent effect of glaze on solvent based digital decorations

ZS Lab
You know that

Digital inks designed for decorating tiles with ink jet printers contain apolar solvents. The glaze applied as a finish coat after decoration is water based, and hence contains polar (and also non-toxic) substances, in contrast with the inks. The difference in polarity in the…

How to level a glaze applied by spray, bell or curtain application?

ZS Lab
You know that

Ceramic glazes and their application systems have not undergone significant change in recent years. In any case, there are various types of additives for levelling the glaze and which can be used in various ways depending on the type of application and the characteristics of the…

How to increase the mechanical strength of green or dried ceramic tiles and slabs

ZS Lab
You know that

The mechanical strength of ceramic tiles and slabs – dried or green – is critical to avoid reducing production. Reductions in production caused by breakages and other defects are often only visible after firing. The advent of digital decoration technology has gradually changed…

What characteristics the grinding water should have to yield a dense slurry?

ZS Lab
You know that

The water used for grinding ceramic pastes plays a fundamental role in making a high density slurry with constant characteristics over time. The on-going challenge in ceramics is to maximise the density of the slip to increase production and reduce the energy cost of…

How to treat glaze which is damaged, smelly or rotten due to attack by bacteria or mould?

ZS Lab
You know that

The aqueous suspensions in glazes and all ceramic clay suspensions are prone to attack by bacteria, mould and fungi because they contain large amounts of water, organic products contained in the clay and organic raw materials or additives. These are nutrients for micro-organisms.…

Why water based inks provide higher definition printing than solvent based inks?

ZS Lab
You know that

When water based inks are used in an ink jet printer, the result is a higher definition image. A drop of solvent based ink is composed of 35% pigment and 65% apolar solvents. A drop of water based ink, on the other hand, is composed of 33% pigment, 33% water and 33% non-toxic,…

Why water based digital inks do not emit odours and reduce atmospheric emissions by at least 50%?

ZS Lab
You know that

During combustion, solvent based inks release strong odours which are perceptible by people. Water based inks have now been developed which do not release perceptible combustion odours. What are the differences between the two types of ink that make them behave so differently?

Why water based digital inks do not dry in the print head, even though they are water based?

ZS Lab
You know that

When ink jet print heads are kept in standby for a period of time, the ink at the nozzle outlets is exposed to air. Neither solvent nor water based inks dry on the head.